48 Days Podcast - Dan Miller picks a stack of questions from readers and methodically answers them. While it is unlikely that you will gain a load of new information from this podcast, you will most certainly find that you are on the right track.
TechZing - Justin and Jason discuss startups, entrepreneurship, and business in incredible detail. If you have the time, and a bit of technical inclination, it would be a good idea to catch up on all the past shows while you're at it.
This Week in Google - Google kind of owns the world. Leo Laporte and his gang do a great job of discussing what is going what is currently going on at google.
This week in Tech - If you are even a bit tech minded, this would be a good podcast to follow to keep in touch with where tech is, and where it might be headed.